Artem Milevskiy pounced inside the opening two minutes to shock Barcelona with an instinctive finish from Andriy Shevchenko’s free-kick, but Xavi drew the visitors level with a 33rd-minute equaliser.
The stage was then set for Messi to produce an exquisite free-kick in the 86th minute to clinch victory for Pep Guardiola’s side and send Dynamo Kiev crashing out of the competition.
Videos:
Milevsky goal
Xavi goal
Messi goal